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enalization
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There are 11 letters in ENALIZATION ( A1E1I1L1N1O1T1Z10 )
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AALII
AIOLI
ALANE
ALANT
ALATE
ALIEN
ALINE
ALOIN
ALONE
ANENT
ANILE
ANION
ANNAL
ANOLE
ANTAE
ATONE
AZINE
AZLON
AZOLE
AZOTE
ELAIN
ELINT
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ENTIA
INANE
INION
INLET
LANAI
LATEN
LEANT
LENTO
LIANA
LIANE
LINEN
LININ
LITAI
NATAL
NITON
NONET
NOTAL
OATEN
OLEIN
TALON
TELIA
TELOI
TENIA
TENON
TINEA
TOILE
TOLAN
TONAL
TONNE
ZLOTE
ZOEAL
ZONAE
ZONAL
4 letters out of ENALIZATION
AEON
ALAE
ALAN
ALIT
ALOE
ALTO
ANAL
ANIL
ANNA
ANOA
ANON
ANTA
ANTE
ANTI
AZAN
AZON
ELAN
ENOL
ETNA
ILEA
ILIA
INIA
INTI
INTO
IOTA
LAIN
LANE
LATE
LATI
LAZE
LEAN
LENO
LENT
LIEN
LINE
LINN
LINO
LINT
LION
LITE
LOAN
LOIN
LONE
LOTA
LOTI
NAAN
NAIL
NALA
NANA
NAOI
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NEAT
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NINE
NITE
NOEL
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NONA
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NOTE
OLEA
TAEL
TAIL
TAIN
TALA
TALE
TALI
TEAL
TELA
TILE
TINE
TOEA
TOIL
TOLA
TOLE
TONE
ZEAL
ZEIN
ZETA
ZINE
ZITI
ZOEA
ZONA
ZONE
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Enalization might refer to |
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In organic chemistry, Keto–enol tautomerism refers to a chemical equilibrium between a keto form (a ketone or an aldehyde) and an enol (an alcohol). The enol and keto forms are said to be tautomers of each other. The interconversion of the two forms involves the movement of an alpha hydrogen and the shifting of bonding electrons; hence, the isomerism qualifies as tautomerism. * A compound containing a carbonyl group (C=O) is normally in rapid equilibrium with an enol tautomer, which contains a pair of doubly bonded carbon atoms adjacent to a hydroxyl (−OH) group, C=C-OH. The keto form predominates at equilibrium for most ketones. Nonetheless, the enol form is important for some reactions. The deprotonated intermediate in the interconversion of the two forms, referred to as an enolate anion, is important in carbonyl chemistry, in large part because it is a strong nucleophile. * Normally, the keto–enol tautomerization chemical equilibrium is highly thermodynamically driven, and at room temperature the equilibrium heavily favors the formation of the keto form. A classic example for favoring the keto form can be seen in the equilibrium between vinyl alcohol and acetaldehyde (K = [enol]/[keto] ≈ 3 × 10−7). However, it is reported that in the case of vinyl alcohol, formation of a stabilized enol form can be accomplished by controlling the water concentration in the system and utilizing the kinetic favorability of the deuterium produced kinetic isotope effect (kH+/kD+ = 4.75, kH2O/kD2O = 12). Deuterium stabilization can be accomplished through hydrolysis of a ketene precursor in the presence of a slight stoichiometric excess of heavy water (D2O). Studies show that the tautomerization process is significantly inhibited at ambient temperatures ( kt ≈ 10−6 M/s), and the half life of the enol form can easily be increased to t1/2 = 42 minutes for first order hydrolysis kinetics. |