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crilege
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There are 7 letters in CRILEGE ( C3E1G2I1L1R1 )
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| Crilege might refer to |
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| The Criegee oxidation is a glycol cleavage reaction in which vicinal diols are oxidized to form ketones and aldehydes using lead tetraacetate. It is analogous but milder than the Malaprade reaction. This oxidation was discovered by Rudolf Criegee and coworkers and first reported in 1931; their seminal publication investigated the oxidative cleavage of glycol.* The rate of the reaction is highly dependent on the conformation of the diols, so much so that diols that are cis on certain rings can be reacted selectively as opposed to those that are trans on them. It was heavily stressed by Criegee that the reaction must be run in anhydrous solvents, as any water present would hydrolyze the lead tetraacetate; however, subsequent publications have shown that if the oxidation is faster than the rate of hydrolysis, the cleavage can be run in wet solvents or even aqueous solutions. For example, gluose, glycerol, mannitol, and xylose can all undergo a Criegee oxidation in aqueous solutions, but sucrose cannot. |