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arsenite
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Definitions of arsenite in various dictionaries:
noun - a chemical salt
ARSENITE - In chemistry, an arsenite is a chemical compound containing an arsenic oxoanion where arsenic has oxidation state +3. Note that in fields that common...
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Any oxyanion of trivalent arsenic, especially the AsO33- anion (or protonated derivatives) Any salt containing this anion, or any ester of arsenious acid |
Arsenite description |
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In chemistry, an arsenite is a chemical compound containing an arsenic oxoanion where arsenic has oxidation state +3. Note that in fields that commonly deal with groundwater chemistry, arsenite is used generically to identify soluble AsIII anions. IUPAC have recommended that arsenite compounds are to be named as arsenate(III), for example ortho-arsenatite is called trioxidoarsenate(III). * Ortho-arsenite contrasts to the corresponding anions of the lighter members of group 15, phosphite which has the structure HPO23 and nitrite, NO2 which is bent.A number of different arsenite anions are known:* AsO33 ortho-arsenite, an ion of arsenous acid, with a pyramidal shape * [AsO2]n meta-arsenite, a polymeric chain anion. * As2O45 pyro-arsenite, O2AsOAsO2 * As3O57 a polyarsenite, [O2AsOAs(O)OAsO2] * As4O69 a polyarsenite, [O2AsOAs(O)OAs(O)OAsO2] * [As6O411]n, a polymeric anionIn all of these the geometry around the AsIII centers are approximately trigonal, the lone pair on the arsenic atom is stereochemica |