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kineticist
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Kineticist might refer to |
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The Kinetic isotope effect (KIE) is the change in the reaction rate of a chemical reaction when one of the atoms in the reactants is replaced by one of its isotopes. Formally, it is the ratio of rate constants for the reactions involving the light (kL) and the heavy (kH) isotopically substituted reactants:* * * * K * I * E * = * * * * k * * L * * * * k * * H * * * * * * * {\displaystyle KIE={\frac {k_{L}}{k_{H}}}} * This change in rate results from heavier isotopologues having a lower velocity/mobility and an increased stability from the higher dissociation energies when compared to the compounds containing lighter isotopes. The study of kinetic isotope effects can help the elucidation of the reaction mechanism of certain chemical reactions. |