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ketonic

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The answer KETONIC has 1 possible clue(s) in existing crosswords.

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Definitions of ketonic in various dictionaries:

adj - a type of chemical compound [n -S] : KETONIC

KETONIC - Ketonic decarboxylation (also known as ketonization) is a type of organic reaction and a decarboxylation converting two equivalents of a carboxylic a...

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Possible Crossword Clues
Of an organic compound

Last Seen in these Crosswords & Puzzles
Sep 18 2005 The Telegraph - General Knowledge

Possible Dictionary Clues
Of, relating to, or being a ketone.

Ketonic description
Ketonic decarboxylation (also known as ketonization) is a type of organic reaction and a decarboxylation converting two equivalents of a carboxylic acid to a symmetric ketone by the application of heat with expulsion of one equivalent of water and one equivalent of carbon dioxide. Bases promote this reaction. The reaction mechanism likely involves nucleophilic attack of the alpha-carbon of one acid group on the other acid group's carbonyl, possibly as a concerted reaction with the decarboxylation. The initial formation of an intermediate carbanion with decarboxylation from one acid group prior to the nucleophilic attack has been proposed, but is unlikely since the byproduct resulting from the carbanion's protonation by the acid has never been reported. This reaction is different from oxidative decarboxylation, which proceeds through a radical mechanism and is characterised by a different product distribution in isotopic labeling experiments with two different carboxylic acids. With two different carboxylic acids, the reaction behaves poorly because of poor selectivity except when one of the acids (for example, a small, volatile one) is used in large excess.

Ketonic description

Ketonic decarboxylation (also known as ketonization) is a type of organic reaction and a decarboxylation converting two equivalents of a carboxylic acid to a symmetric ketone by the application of heat with expulsion of one equivalent of water and one equivalent of carbon dioxide. Bases promote this reaction. The reaction mechanism likely involves nucleophilic attack of the alpha-carbon of one acid group on the other acid group's carbonyl, possibly as a concerted reaction with the decarboxylation. The initial formation of an intermediate carbanion with decarboxylation from one acid group prior to the nucleophilic attack has been proposed, but is unlikely since the byproduct resulting from the carbanion's protonation by the acid has never been reported. This reaction is different from oxidative decarboxylation, which proceeds through a radical mechanism and is characterised by a different product distribution in isotopic labeling experiments with two different carboxylic acids. With two different carboxylic acids, the reaction behaves poorly because of poor selectivity except when one of the acids (for example, a small, volatile one) is used in large excess.

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